The five baseline polymers used in industrial pneumatic tubing are polyurethane (PU), nylon, polyethylene (PE), polyvinyl chloride (PVC), and polytetrafluoroethylene (PTFE), with polypropylene and specialty fluororesins filling narrower roles [S1][S4][S6].
Selection in practice is driven by routing method, working pressure, temperature, chemical exposure, and the OD needed to mate with push-to-connect fittings, rather than by marketing claims about a single "best" material [S5][S4]. Tubing OD typically runs 1/8 to 1/2 in (3.2 to 12 mm), and that OD is the controlling dimension for fitting interchangeability [S4][S2].
Polyurethane (PU): the flexible default for dynamic routing
PU is the most flexible of the common pneumatic tubing polymers and combines plastic durability with rubber-like elasticity, giving excellent kink and abrasion resistance plus chemical compatibility with petroleum products [S6][S4]. Working pressure is rated at 150 psi or higher, sufficient for most plant-air branch circuits, and PU is also the polymer that SMC specifies in its moisture-control (IDK) tubing where water-vapor diffusion matters [S4][S2].
PU is the first choice where the line moves with the machine: robotic end-of-arm tooling, pick-and-place axes, and any circuit that flexes more than a few thousand cycles per shift. Hardness is tunable (Freelin-Wade Fre-Thane is offered in multiple durometer values), and the material resists hydrolysis, which is why it also shows up in humid factory cells [S1][S2].
Nylon: the fixed-run, high-pressure workhorse
Nylon tolerates working pressure up to roughly 800 psi (size-dependent) and continuous temperatures to 200°F, well above PE or PVC, and is the polymer SMC recommends for fixed plant-air distribution [S4]. It is semi-rigid, chemical-resistant, and stress-crack-resistant, but it does not like tight bend radii, which is why routing geometry, not raw pressure rating, drives the PU-versus-nylon call [S5].
Nylon-11 variants are listed as food-grade, and natural or coloured nylon dominates compressed-air manifolds, HVAC control lines, and any long straight run where the tube is clipped once and never moved [S1][S4]. Expect a higher unit cost than PE or PVC in exchange for the pressure and temperature headroom.
Polyethylene (PE) and PVC: low-pressure, low-cost branch circuits

PE (LDPE) pneumatic tubing is lightweight, chemically inert, and gas/moisture impermeable, which makes it common in food and beverage, medical, and agricultural fluid handling [S1][S4]. The trade-off is a 125 psi working-pressure ceiling (size-dependent), a limited temperature window, and a tendency to kink if over-bent, so PE is rarely used on the main air main itself [S4].
PVC sits one step up in flexibility and chemical breadth: low cost, clear as standard for visual flow checks, sterilizable, and resistant to a wide range of fluids, but not as mechanically tough as PU [S4]. PVC is a common call for low-pressure branch lines and instrument air where the run is fixed and visibility into the line is useful.
PTFE, polypropylene, and specialty polymers
PTFE is the polymer of last resort before hoses: rated to roughly 500°F, exceptionally corrosion-resistant, and specified where acids, bases, or ultrapure water rule out every other thermoplastic [S4][S2]. Polypropylene is the lightest thermoplastic in the family, offers superior dimensional stability and UV resistance, and survives sterilisation above 212°F, which is why it shows up in food plants and outdoor skids [S4].
Beyond the five baseline polymers, engineered variants solve specific failure modes: spark-resistant tubing with a UL-94 V-0 outer layer for welding cells, wear-resistant grades for high-cycle tight-bend routing, and moisture-control tubes that diffuse water vapour before it condenses inside small cylinders and air-operated valves [S2]. These are application-specific overlays on the same five-polymer base, not separate categories, and they should be specified against the failure mode first, then the polymer.
Selection mapping: routing x operating conditions

The selection matrix published by SHPI ties polymer to routing geometry and operating envelope, and it is the cleanest working model for procurement [S5]. Dynamic routing maps to PU, fixed long runs map to nylon, low-pressure fluid transfer maps to LDPE, higher working pressure maps to reinforced PU hose, retractable and space-saving applications map to coiled PU, commercial-vehicle air brakes map to dedicated air-brake tubing, and spark/heat exposure maps to anti-spark tubing [S5].
For a like-for-like comparison, the engineering shortlist is: PU (flexibility, 150+ psi, hydrolysis-resistant) versus nylon (semi-rigid, up to 800 psi, 200°F) versus PE/PVC (low cost, low pressure, food-grade options) versus PTFE (500°F, full chemical resistance). On cost per foot the order is PE/PVC < PU < nylon < PTFE; on temperature ceiling the order is PE < PVC < nylon < PTFE; on flexibility the order inverts, with PU on top [S4].
Size, standards, and sourcing notes
Tubing is specified by outside diameter to maintain push-to-connect fitting compatibility, with common ODs of 1/8, 5/32, 3/16, 1/4, 5/16, 3/8, 1/2 in (3.2, 4, 6, 8, 10, 12, 16 mm), and main air-supply circuits typically sized 1/4 to 1/2 in OD while branch circuits to cylinders and actuators run 1/8 to 3/8 in OD [S4][S2]. Hose, by contrast, is specified by inner diameter and usually arrives with end fittings pre-attached, and is sized 1/4, 3/8, 1/2 in ID for shop-air duty [S4].
Distributor inventory from Freelin-Wade (Fre-Thane PU, nylon, PE, PVC), Festo's pneumatic-tubes catalogue, and SMC's moisture-control line all confirm the same five-polymer baseline, with the same OD-based fitting interface, which is the practical interoperability guarantee for a multi-vendor plant [S1][S3][S2]. For buyers cross-referencing pneumatic components, the related spec map on pneumatic silencer TCO covers the exhaust-side hardware that shares the same polymer selection logic, and the broader pneumatic reference frames the system-level trade-offs. Where the tubing terminates into motion components, pneumatic actuators carry their own pressure and temperature envelopes that the upstream tube must support, not the other way around.
Trackable signals for the next procurement cycle: the UL-94 V-0 spark-resistant sub-category expanding out of welding-cell retrofits, wider stocking of nylon-11 food-grade SKUs, and growing IDK-style moisture-control tube adoption in small-cylinder machine cells [S2]. Each maps to a specific failure mode (sparks, washdown, condensation) rather than a generic "better tubing" pitch.
Spec-level background on the components involved: pneumatic tubing.